Epoxidation of Terminalia catappa L. Seed oil: Optimization reaction

Authors : Erin Ryantin Gunawan; Murniati Murniati; Dedy Suhendra; Petryana Arimanda; Dina Asnawati
article cite 22 Year 2022
source: South African Journal of Chemical Engineering
Abstract

Unsaturated fatty acids contained in vegetable oils can be used as a raw material to produce epoxy through epoxidation reactions. This study aims to obtain the optimum conditions for the epoxidation reaction of Terminalia catappa L. (local name “ketapang”) seed oil. In this study, the epoxidation reaction was carried out by reacting the ketapang seed oil and a mixture of formic acid and hydrogen peroxide, and sulfuric acid as a catalyst. The optimum reaction conditions obtained were reaction temperature of 45 °C, reaction time of 5 h, and reactants molar ratio of 1:4:5 (mol/mol). The percentage of the oxirane oxygen content of the products synthesized using the optimum reaction conditions was 3.46% with the percentage relative conversion to oxirane of 78%.


Concepts :
Enzyme Catalysis and Immobilization
Biodiesel Production and Applications
Edible Oils Quality and Analysis
article cite 22 Year 2022 source South African Journal of Chemical Engineering
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